The Fundamentals Of Thermodynamics

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Fundamentals of Thermodynamics and Applications

Author: Ingo Müller
language: en
Publisher: Springer Science & Business Media
Release Date: 2009-03-12
Thermodynamics is the much abused slave of many masters • physicists who love the totally impractical Carnot process, • mechanical engineers who design power stations and refrigerators, • chemists who are successfully synthesizing ammonia and are puzzled by photosynthesis, • meteorologists who calculate cloud bases and predict föhn, boraccia and scirocco, • physico-chemists who vulcanize rubber and build fuel cells, • chemical engineers who rectify natural gas and distil f- mented potato juice, • metallurgists who improve steels and harden surfaces, • - trition counselors who recommend a proper intake of calories, • mechanics who adjust heat exchangers, • architects who construe – and often misconstrue – ch- neys, • biologists who marvel at the height of trees, • air conditioning engineers who design saunas and the ventilation of air plane cabins, • rocket engineers who create supersonic flows, et cetera. Not all of these professional groups need the full depth and breadth of ther- dynamics. For some it is enough to consider a well-stirred tank, for others a s- tionary nozzle flow is essential, and yet others are well-served with the partial d- ferential equation of heat conduction. It is therefore natural that thermodynamics is prone to mutilation; different group-specific meta-thermodynamics’ have emerged which serve the interest of the groups under most circumstances and leave out aspects that are not often needed in their fields.
Fundamentals of Thermodynamics

A concise treatment of the fundamentals of thermodynamics is presented in this book. In particular, emphasis is placed on discussions of the second law, a unique feature of thermodynamics, which states the limitations of converting thermal energy into mechanical energy. The entropy function that permits the loss in the potential of a real thermodynamic process to be assessed, the maximum possible work in a process, and irreversibility and equilibrium are deduced from the law through physical and intuitive considerations. They are applicable in mitigating waste heat and are useful for solving energy, power, propulsion and climate-related issues. The treatment is not restricted to properties and functions of ideal gases. The ideal gas assumption is invoked as a limiting case. Reversible paths between equilibrium states are obtained using reversible heat engines and reversible heat pumps between environment and systems to determine the entropy changes and the maximum work. The conditions of thermodynamic equilibrium comprising mechanical, thermal, chemical and phase equilibrium are addressed and the species formed at equilibrium in a chemical reaction at a given temperature and pressure are obtained. The molecular basis for the laws of thermodynamics, temperature, internal energy changes, entropy, reversibility and equilibrium are briefly discussed. The book serves as a reference for undergraduate and graduate students alongside thermodynamics textbooks.
Essentials of Thermodynamics

Author: N.D. Hari Dass
language: en
Publisher: SRI Books, an imprint of the Simplicity Research Institute
Release Date: 2021-02-21
Essentials of Thermodynamics offers a fresh perspective on classical thermodynamics and its explanation of natural phenomena. It combines fundamental principles with applications to offer an integrated resource for students, teachers and experts alike. The essence of classic texts has been distilled to give a balanced and in-depth treatment, including a detailed history of ideas which explains how thermodynamics evolved without knowledge of the underlying atomic structure of matter. The principles are illustrated by a vast range of applications, such as osmotic pressure, how solids melt and liquids boil, the incredible race to reach absolute zero, and the modern theme of the renormalization group. Topics are handled using a variety of techniques, which helps readers see how concepts such as entropy and free energy can be applied to many situations, and in diverse ways. The book has a large number of solved examples and problems in each chapter, as well as a carefully selected guide to further reading. The treatment of traditional topics like the three laws of thermodynamics, Carnot cycles, Clapeyron equation, phase equilibria, and dilute solutions is considerably more detailed than usual. For example, the chapter on Carnot cycles discusses exotic cases like the photon cycle along with more practical ones like the Otto, Diesel and Rankine cycles. There is a chapter on critical phenomena that is modern and yet highly pedagogical and contains a first principles calculation of the critical exponents of Van der Waals systems. Topics like entropy constants, surface thermodynamics, and superconducting phase transitions are explained in depth while maintaining accessibility for different readers.