The Equilibrium Theory Of Inhomogeneous Polymers
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The Equilibrium Theory of Inhomogeneous Polymers
The Equilibrium Theory of Inhomogeneous Polymers provides an introduction to the field-theoretic methods and computer simulation techniques that are used in the design of structured polymeric fluids. By such methods, the principles that dictate equilibrium self-assembly in systems ranging from block and graft copolymers, to polyelectrolytes, liquid crystalline polymers, and polymer nanocomposites can be established. Building on an introductory discussion of single-polymer statistical mechanics, the book provides a detailed treatment of analytical and numerical techniques for addressing the conformational properties of polymers subjected to spatially-varying potential fields. This problem is shown to be central to the field-theoretic description of interacting polymeric fluids, and models for a number of important polymer systems are elaborated. Chapter 5 serves to unify and expound the topic of self-consistent field theory, which is a collection of analytical and numerical techniques for obtaining solutions of polymer field theory models in the mean-field approximation. The concluding Chapter 6 provides a discussion of analytical methods for going beyond the mean-field approximation and an introduction to the exciting new field of field-theoretic polymer simulations - the direct numerical simulation of polymer field theory models. No other book brings together in such a detailed and instructive fashion the theoretical and numerical tools for investigating the equilibrium structure and thermodynamics of meso-structured polymer formulations, including those relevant to soft material nanotechnologies, personal care products, and multiphase plastic materials.
The Equilibrium Theory of Inhomogeneous Polymers
This work provides a pedagogical introduction to the theoretical and computer simulation techniques that are useful in the design of polymer formulations including personal care products multiphase plastic materials and processed foods.
The Physics of Polymers
Author: Gert R. Strobl
language: en
Publisher: Springer Science & Business Media
Release Date: 2007-08-02
Polymer physics is a key part of macromolecular science. This textbook presents the elements of this important branch of materials science in the style of a series of lecture. The main focus lays on the concepts, rather than on experimental techniques and theoretical methods. Written for graduate students of physics, materials science and chemical engineering, as well as for researchers in academia and industry entering this field, the book introduces and discusses the basic phenomena that lead to the peculiar physical properties of polymeric systems. After more than ten years since the first printing, the time had come for a revision and expansion of the book's contents. In addition to numerous minor modifications, this third edition includes some major changes: (i) A newly written chapter deals with conjugated polymers. The physical basis of the characteristic electro-optic response is explained, and the spectacular electrical conduction properties of conjugated polymers created by doping are discussed. (ii) Polyelectrolyte solutions with their special properties caused by Coulomb forces are newly treated in different chapters of the book dealing with ordering phenomena, viscous effects and the superswelling of gels. (iii) Since the basic understanding of melt crystallization has greatly changed during the last decade, the corresponding chapter was rewritten. It presents the new findings and interprets the discovered laws.