Structural Crystallography Of Inorganic Oxysalts
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Structural Crystallography of Inorganic Oxysalts
This book is the first book dealing with structural crystallography of inorganic oxysalts in general. A special emphasis is placed upon structural topology and methods of its description. The latter include graph theory, nets, 2-D and 3-D tilings, polyhedra, etc. The structures considered range from minerals to organically templated oxysalts, for all of which this book provides a unified approach to structure interpretation and classification. Most of the structures have been analysed from the proposed viewpoint for the first time and it has been shown that they possess the same topological genealogy and relationships, sometimes despite their obvious chemical differences. In order to expand the range of oxysalts considered, the book offers not only traditional schemes but also alternative approaches such as anion topologis, anion-centered polyhedra and cation arrays. As such, this book can be considered as a comprehensive introduction into the amazingly complex and diverse world of inorganic oxysalts.
The Chemical Bond in Inorganic Chemistry
The bond valence model, a description of acid-base bonding, is widely used for analysing and modelling the structures and properties of solids and liquids. Unlike other models of inorganic chemical bonding, the bond valence model is simple, intuitive, and predictive, and is accessible to anyone with a pocket calculator and a secondary school command of chemistry and physics. This new edition of 'The Chemical Bond in Inorganic Chemistry: The Bond Valence Model' shows how chemical properties arise naturally from the conflict between the constraints of chemistry and those of three-dimensional space. The book derives the rules of the bond valence model, as well as those of the traditional covalent, ionic and popular VSEPR models, by identifying the chemical bond with the electrostatic flux linking the bonded atoms. Most of the new edition is devoted to showing how to apply these ideas to real materials including crystals, liquids, glasses and surfaces. The work includes detailed examples of applications, and the final chapter explores the relationship between the flux and quantum theories of the bond.
Inorganic 3D Structures
Author: Angel Vegas
language: en
Publisher: Springer Science & Business Media
Release Date: 2011-06-17
D. Santamaría-Pérez and F. Liebau : Structural relationships between intermetallic clathrates, porous tectosilicates and clathrates hydrates Vladislav A. Blatov: Crystal structures of inorganic oxoacid salts perceived as cation arrays: a periodic graph approach Ángel Vegas: FeLiPO4: Dissection of a crystal structure. The parts and the whole D. J. M. Bevan, R. L. Martin, Ángel Vegas: Rationalisation of the substructures derived from the three fluorite-related [Li6(MVLi)N4] polymorphs: An analysis in terms of the “Bärnighausen Trees” and of the “Extended Zintl-Klemm Concept” Ángel Vegas: Concurrent pathways in the phase transitions of alloys and oxides: Towards an Unified Vision of Inorganic Solids