Principles Of Stable Isotope Distribution
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Principles of Stable Isotope Distribution
Author: R. E. Criss
language: en
Publisher: Oxford University Press
Release Date: 1999-06-03
1. Abundance and Measurement of Stable Isotopes. 1.1. Discovery of Isotopes. 1.2. Nuclide Types, Abundances, and Atomic Weights. 1.3. Properties and Fractionation of Isotopic Molecules. 1.4. Material Balance Relationships. 1.5. Mass Spectrometers. 1.6. Notation and Standards. 1.7. Summary. 1.8. Problems. References. 2. Isotopic Exchange and Equilibrium Fractionation. 2.1. Isotopic Exchange Reactions. 2.2. Basic Equations. 2.3. Molecular Models. 2.4. Theory of Isotopic Fractionation. 2.5. Temperature Dependence of Isotopic Fractionation Factors. 2.6. Rule of the Mean. 2.7. Isotopic Thermometers.
Principles of Stable Isotope Distribution
Author: Robert E. Criss
language: en
Publisher: Oxford University Press
Release Date: 1999-06-03
This book presents a quantitative treatment of the theory and natural variations of light stable isotopes. It discusses isotope distribution in the context of fractionation processes, thermodynamics, mass conservation, exchange kinetics, and diffusion theory, and includes more than 100 original equations. The theoretical principles are illustrated with natural examples that emphasize oxygen and hydrogen isotope variations in natural waters, terrestrial and extraterrestrial rocks, and hydrothermal systems. New data on meteoric precipitation, rivers, springs, formation fluids, and hydrothermal systems are included in relation to various natural phenomena. Essentially, this book seeks to reconnect the diverse phenomenological observations of isotope distribution to the quantitative theories of physical chemistry and the language of differential equations. It may serve as a textbook for advanced students, as a research reference, or as a quick source of information. The book is organized into five chapters, each followed by suggested quantitative problems and a short reference list. The three theoretical chapters progress from an elementary review of the physical chemistry of stable isotopes, to the thermodynamics of isotopic compounds, and finally to the calculation of isotope distribution in dynamic systems. The third and fifth chapters emphasize oxygen and hydrogen isotope variations in Earth's hydrosphere and lithosphere, constituting the most important examples of the theoretical principles. Appendices provide data on atomic weights of light elements, physical constants, mathematical relationships, and isotopic fractionation factors.
Principles of Stable Isotope Geochemistry
This is the first dedicated book to cover the basics of a wide range of stable isotope applications in a manner appropriate for someone entering the field. At the same time, it offers sufficient detail - and numerous references and examples - to direct research for further inquiry. Discusses diverse topics such as hydrology, carbon in plants, meteorites, carbonates, metamorphic rocks, etc. Explores the theory and principles of isotope fractionation. Offers unique, up-to-date discussion of meteorite (extraterrestrial) isotope data. Presents the subject in an interesting historical context, with the classic papers noted. A useful reference for students taking the course and professionals entering the field of Geochemistry.