Predictive Statistical Mechanics

Predictive Statistical Mechanics

Chapters 1 to 5 include a description of the philosophy, foundations, and construction (methodology) of the formalism, including the derivation of a nonequilibrium grand-canonical ensemble for far-from-equilibrium systems as well as the derivation of a quantum nonlinear kinetic theory and a response function theory together with a theory of scattering. In chapter 6 applications of the theory are cataloged, making comparisons with experimental data (a basic step for the validation of any theory). Chapter 7 is devoted to the description of irreversible thermodynamics, providing a far-reaching generalization of Informational-Statistical Thermodynamics. The last chapter gives an overall picture of the formalism, and questions and criticisms related to it are discussed.

Predictive Statistical Mechanics

E.T. Jaynes

The first six chapters of this volume present the author's 'predictive' or information theoretic' approach to statistical mechanics, in which the basic probability distributions over microstates are obtained as distributions of maximum entropy (Le. , as distributions that are most non-committal with regard to missing information among all those satisfying the macroscopically given constraints). There is then no need to make additional assumptions of ergodicity or metric transitivity; the theory proceeds entirely by inference from macroscopic measurements and the underlying dynamical assumptions. Moreover, the method of maximizing the entropy is completely general and applies, in particular, to irreversible processes as well as to reversible ones. The next three chapters provide a broader framework - at once Bayesian and objective - for maximum entropy inference. The basic principles of inference, including the usual axioms of probability, are seen to rest on nothing more than requirements of consistency, above all, the requirement that in two problems where we have the same information we must assign the same probabilities. Thus, statistical mechanics is viewed as a branch of a general theory of inference, and the latter as an extension of the ordinary logic of consistency. Those who are familiar with the literature of statistics and statistical mechanics will recognize in both of these steps a genuine 'scientific revolution' - a complete reversal of earlier conceptions - and one of no small significance.