Mechanisms Of Inorganic Reactions
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Mechanisms of Inorganic Reactions
Author: Dimitris Katakis
language: en
Publisher: Wiley-Interscience
Release Date: 1987-05-14
Offers complete coverage of basic inorganic reaction mechanisms that brings readers up to date on developments in the field. Mechanistic concepts introduced will provoke consideration of larger categories of inorganic reactions without the need for expert knowledge. Theoretical and experimental methods are described, as well as the possibilities offered by each technique, the kind of information obtained, the limitations of each, and methods for handling experimental data. Carefully clarifies the relationship between mechanism and kinetics, and corresponding concepts. Features a chapter on inorganic photochemistry and the related energy conversion--a branch of inorganic reaction mechanisms that is making rapid advances.
Chemical Kinetics and Inorganic Reaction Mechanisms
Author: Smiljko Asperger
language: en
Publisher: Springer Science & Business Media
Release Date: 2011-06-27
The serious study of the reaction mechanisms of transition metal com plexes began some five decades ago. Work was initiated in the United States and Great Britain; the pioneers ofthat era were, inalphabetical order, F. Basolo, R. E. Connick, 1. O. Edwards, C. S. Garner, G. P.Haight, W. C. E. Higgision, E.1. King, R. G. Pearson, H. Taube, M.1. Tobe, and R. G. Wilkins.A larger community of research scientists then entered the field, many of them stu dents ofthose just mentioned. Interest spread elsewhere as well, principally to Asia, Canada, and Europe. Before long, the results ofindividual studies were being consolidated into models, many of which traced their origins to the better-established field of mechanistic organic chemistry. For a time this sufficed, but major revisions and new assignments of mechanism became necessary for both ligand sub stitution and oxidation-reduction reactions. Mechanistic inorganic chemistry thus took on a shape of its own. This process has brought us to the present time. Interests have expanded both to include new and more complex species (e.g., metalloproteins) and a wealth of new experimental techniques that have developed mechanisms in ever-finer detail. This is the story the author tells, and in so doing he weaves in the identities of the investigators with the story he has to tell. This makes an enjoyable as well as informative reading.
Inorganic and Organometallic Reaction Mechanisms
This title provides detailed coverage of classic inorganic reaction mechanisms and organometallic reaction mechanisms. The coverage of the mechanisms expected for reactions of transitions metal complex includes the kinetic studies used to differentiate possible mechanisms. This combination of coordination complexes and organometallic complexes is unique to this title. Describing how transition metal complexes react and the type of data used to determine how complexes react, this work provides excellent introductions, extensive problems, and thought-provoking summaries in every chapter. Complete with excellent references, this second edition has been updated with new problems and increased information on NMR techniques, dissociative reactions of square-planar complexes, seventeen-electron complexes, organometallic transfer, and oxidative-addition and reductive-elimination reactions. The only current text on inorganic mechanisms, this book is ideal for students and chemists who deal with inorganic and organometallic reagents.