Introduction To The Theory Of Ion Atomic Collisions

Lectures on Ion-Atom Collisions

Atomic collisions offer some unique opportunities to study atomic structure and reaction mechanisms in experiment and theory, especially for projectiles of high atomic number provided by modern accelerators. The book is meant as an introduction into the field and provides some basic theoretical understanding of the atomic processes occurring when a projectile hits another atom. It also furnishes the tools for a mathematical description, however, without going deeper into the technical details, which can be found in the literature given. With this aim, the focus is on reactions, in which only a single active electron participates. Collisional excitation, ionization and charge transfer are discussed for collision velocities ranging from slow to comparable to thespeed of light. For the highest projectile velocities, energy can be converted into mass, so that electron-positron pairs are created. In addition to the systematic treatment, a theoretical section specializes on electron-electroncorrelations and three chapters are devoted to selected highlights bordering to surface science and to physics with antiprotons.* Simple access to the theory of collisions between ions and atoms* Systematic treatment of basic features needed for an understanding* Mathematical details are omitted and referred to references* In order to bear out the essential ideas most clearly, a single active electron is assumed in most cases* In selected examples, theoretical results are confronted with experiment* Discussion supported by a large number of illustrations* Selected highlights in borderline fields are presented

Introduction to the Theory of Ion-atomic Collisions

Collision Spectroscopy

R. G. Cooks This introduction has three purposes: (a) to summarize some of the chief features of energy spectrometry of ions and to sketch in a little of the background to this subject, (b) to present some simple facts about collision processes which one skilled in, say, mass spectrometry but innocent of any knowledge of bimolecular collisions might find of value, and (c) to indicate the scope and content of the volume. 1. The Subject This book takes as its subject, ion-molecule and ion-atom reactions occurring at high energies. It emphasizes the study of inelastic reactions at high energy through measurements of translational energy. The investiga tion of these reactions using other procedures has been important in the cases of the simpler systems. In particular, the emitted radiation has been investigated and this subject is therefore discussed where appropriate. For more complex species, however, there is little information available other than from energy spectra. The defining characteristic of the energy range of interest is that momentum transfer to the neutral target is negligible for small scattering angles. The result of this apparently bland condition is a welcome simplicity in the interpretation of the results of what appears to be developing into a R. G. Cooks • Department of Chemistry, Purdue University, West Lafayette, Indiana 47907. 2 Introduction unique form of spectroscopy. The names ion kinetic-energy spectrometry, translational energy spectrometry, collision spectroscopy, and energy-loss spectrometry have all been used to describe this subject (d. Section 5).