Group Theory And Quantum Mechanics
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Group Theory and Quantum Mechanics
Author: Bartel L. van der Waerden
language: en
Publisher: Springer Science & Business Media
Release Date: 2012-12-06
The German edition of this book appeared in 1932 under the title "Die gruppentheoretische Methode in der Quantenmechanik". Its aim was, to explain the fundamental notions of the Theory of Groups and their Representations, and the application of this theory to the Quantum Mechanics of Atoms and Molecules. The book was mainly written for the benefit of physicists who were supposed to be familiar with Quantum Mechanics. However, it turned out that it was also used by. mathematicians who wanted to learn Quantum Mechanics from it. Naturally, the physical parts were too difficult for mathematicians, whereas the mathematical parts were sometimes too difficult for physicists. The German language created an additional difficulty for many readers. In order to make the book more readable for physicists and mathe maticians alike, I have rewritten the whole volume. The changes are most notable in Chapters 1 and 6. In Chapter t, I have tried to give a mathematically rigorous exposition of the principles of Quantum Mechanics. This was possible because recent investigations in the theory of self-adjoint linear operators have made the mathematical foundation of Quantum Mechanics much clearer than it was in t 932. Chapter 6, on Molecule Spectra, was too much condensed in the German edition. I hope it is now easier to understand. In Chapter 2-5 too, numerous changes were made in order to make the book more readable and more useful.
The Theory of Groups and Quantum Mechanics
This landmark among mathematics texts applies group theory to quantum mechanics, first covering unitary geometry, quantum theory, groups and their representations, then applications themselves — rotation, Lorentz, permutation groups, symmetric permutation groups, and the algebra of symmetric transformations.
Group Theory in Quantum Mechanics
Group Theory in Quantum Mechanics: An Introduction to its Present Usage introduces the reader to the three main uses of group theory in quantum mechanics: to label energy levels and the corresponding eigenstates; to discuss qualitatively the splitting of energy levels as one starts from an approximate Hamiltonian and adds correction terms; and to aid in the evaluation of matrix elements of all kinds, and in particular to provide general selection rules for the non-zero ones. The theme is to show how all this is achieved by considering the symmetry properties of the Hamiltonian and the way in which these symmetries are reflected in the wave functions. This book is comprised of eight chapters and begins with an overview of the necessary mathematical concepts, including representations and vector spaces and their relevance to quantum mechanics. The uses of symmetry properties and mathematical expression of symmetry operations are also outlined, along with symmetry transformations of the Hamiltonian. The next chapter describes the three uses of group theory, with particular reference to the theory of atomic energy levels and transitions. The following chapters deal with the theory of free atoms and ions; representations of finite groups; the electronic structure and vibrations of molecules; solid state physics; and relativistic quantum mechanics. Nuclear physics is also discussed, with emphasis on the isotopic spin formalism, nuclear forces, and the reactions that arise when the nuclei take part in time-dependent processes. This monograph will be of interest to physicists and mathematicians.