From Simple Solutions To Strongly Structured Microemulsions
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From Simple Solutions to Strongly Structured Microemulsions
Microemulsions are known for their versatile properties widely utilized in fundamental research and industrial applications. They are thermodynamically stable mixtures structured on a colloidal length scale with an amphiphilic film separating water- and oil-rich domains. However, recent studies claim the existence of “surfactant-free microemulsions,” which exhibit structures on a molecular length scale. By means of systematic phase behavior and scattering experiments, this dissertation provides deep insights into the pathway from simple solutions to weakly and strongly structured microemulsions. With bulk-contrast SANS, the scattering behavior of a simple solution system made of water, cyclohexane, 1- and 2-propanol was found to be dominated by critical composition fluctuations (Ornstein-Zernike). Further analysis of critical phenomena revealed the critical exponent doubling that follows the scaling law γ ~ “2” ν. On the other hand, weak scattering signals described with a new model were detected in the film-contrast SANS data due to the nearby tricritical point (TCP). After crossing the TCP, the formation of well-defined amphiphilic films was demonstrated by increasing the amphiphilicity of the amphiphile. Subsequently, the influence of modifications of the amphiphilic film by adding novel diblock polymers was studied. As a result, enhanced efficiency and strengthened structural ordering were achieved in typical alkane microemulsions and novel CO2 microemulsions. Finally, the properties of industry-relevant microemulsions were investigated in two application-oriented projects. One project focused on the phase behavior and the microstructure of polyol-rich CO2 microemulsions, which can be used for the polyurethane (PU) foam production with cell sizes of a few micrometers. The other project focused on the formulation of optimum microemulsions stabilized by highly efficient extended surfactants. The experimental parameters from phase behavior studies helped determine the coefficients of the HLD equation, which can serve as a prediction tool for tackling a wide variety of formulation problems. Above all, this doctoral dissertation elucidated the pathway toward structured microemulsions and demonstrated versatile aspects of microemulsions’ applications.
Structure and Dynamics of Strongly Interacting Colloids and Supramolecular Aggregates in Solution
Author: Sow-Hsin Chen
language: en
Publisher: Springer Science & Business Media
Release Date: 2012-12-06
During the last decade, various powerful experimental tools have been developed, such as small angle X-ray and neutron scattering, X-ray and neutron reflection from interfaces, neutron spin-echo spectroscopy and quasi-elastic multiple light scattering and large scale computer simulations. Due to the rapid progress brought about by these techniques, one witnesses a resurgence of interest in the physicochemical properties of colloids, surfactants and macromolecules in solution. Although these disciplines have a long history, they are at present rapidly transforming into a new, interdisciplinary research area generally known as complex liquids or soft condensed matter physics: names that reflect the considerable involvement of the chemical and condensed matter physicists. This book is based on lectures given at a NATO ASI held in the summer of 1991 and discusses these new developments, both in theory and experiment. It constitutes the most up-to-date and comprehensive summary of the entire field.
Neutrons, X-rays, and Light
This book addresses the possibilities provided by scattering techniques in the study of soft matter. It fills the gap between the fundamental scattering processes, which are described by the general theoretical framework of elastic and quasi-elastic interaction of radiation with matter, and state-of-the-art applications to specific soft matter systems. Three probes are discussed in detail: neutrons, X-ray photons, and visible light. The first part of the book is dedicated to the use of general principles for the measurement and analysis of scattered intensity: elementary scattering process, data reduction, general theorems, the concept of reciprocal space, and its link to structural and dynamical information in direct space. In the second part, methods and techniques are further discussed, including resolution effects, contrast variation, static and dynamic light scattering, quasi-elastic neutron scattering, and reflectometry and grazing incidence techniques. Part three deals with the state of the art of scattering studies of typical soft matter systems (polymers, self-assembled surfactant systems, microemulsions, liquid crystals, colloids, aggregates, biological systems) with dedicated chapters for particle interactions, and modelling. Part four highlights special applications, from turbid media to scattering under external constraints, and industrial applications. This new edition, written by the lecturers of the Bombannes Summer School, will be most useful as a learning tool for masters and PhD students, post-docs, and young researchers moving into the field. As with the previous edition, it will also be a reference for any scientist working in soft matter, where scattering techniques are ubiquitous, used both in small laboratories and at large-scale research facilities. • Provides an understandable and thorough introduction to the fundamentals of scattering in a way that is accessible for students/PhDs.• Offers a comprehensive overview of the main scattering techniques associated with neutrons, X-rays, and light.• Includes chapters on virtually all soft matter systems.• Presents both standard analyses and recent advances in scattering techniques