From Experimental Kinetic Data To Reaction Mechanisms
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From Experimental Kinetic Data to Reaction Mechanisms
This textbook offers a deep dive into practical kinetics in solution, providing a comprehensive overview of the techniques and methods used to monitor chemical reactions. It addresses fundamental questions about reaction rates, rate laws, and the intricate dynamics of chemical processes. By connecting various experimental aspects required for kinetic and mechanistic research, it guides students on how to obtain, treat, and interpret experimental data to gain realistic mechanistic insights. Divided into nine chapters, the textbook begins with an introduction to the basic concepts of chemical kinetics and an experimental perspective on monitoring chemical reactions. Subsequent chapters cover complex reactions, offering insights into simplifying reaction schemes through steady-state and pre-equilibrium approximations. Special attention is given to reactions in solution, highlighting diffusion-controlled and activation-controlled reactions, as well as the role of catalysis. The authors provide expert analyses of chemical reactivity in multiphasic systems, such as microemulsions and emulsions, offering a detailed understanding of these complex environments. The textbook also focuses on the analysis of kinetic data, including the effects of solution composition. It explores non-linear regression analyses, residuals, dataset size, noise, fitting functions, and the limits of fitting algorithms. Additionally, it presents comparisons between fitting data and experimental data, providing readers with valuable insights. This textbook is an invaluable resource for upper-undergraduate and graduate students conducting research in reaction kinetics. It is also essential for researchers and practitioners in chemistry, particularly those interested in reaction kinetics and chemical reactivity. With contributions from leading experts, this volume is a must-read for anyone looking to advance their understanding of chemical kinetics.
From Experimental Kinetic Data to Reaction Mechanisms
This textbook offers a deep dive into practical kinetics in solution, providing a comprehensive overview of the techniques and methods used to monitor chemical reactions. It addresses fundamental questions about reaction rates, rate laws, and the intricate dynamics of chemical processes. By connecting various experimental aspects required for kinetic and mechanistic research, it guides students on how to obtain, treat, and interpret experimental data to gain realistic mechanistic insights. Divided into nine chapters, the textbook begins with an introduction to the basic concepts of chemical kinetics and an experimental perspective on monitoring chemical reactions. Subsequent chapters cover complex reactions, offering insights into simplifying reaction schemes through steady-state and pre-equilibrium approximations. Special attention is given to reactions in solution, highlighting diffusion-controlled and activation-controlled reactions, as well as the role of catalysis. The authors provide expert analyses of chemical reactivity in multiphasic systems, such as microemulsions and emulsions, offering a detailed understanding of these complex environments. The textbook also focuses on the analysis of kinetic data, including the effects of solution composition. It explores non-linear regression analyses, residuals, dataset size, noise, fitting functions, and the limits of fitting algorithms. Additionally, it presents comparisons between fitting data and experimental data, providing readers with valuable insights. This textbook is an invaluable resource for upper-undergraduate and graduate students conducting research in reaction kinetics. It is also essential for researchers and practitioners in chemistry, particularly those interested in reaction kinetics and chemical reactivity. With contributions from leading experts, this volume is a must-read for anyone looking to advance their understanding of chemical kinetics.
Advanced Organic Chemistry
Author: Francis A. Carey
language: en
Publisher: Springer Science & Business Media
Release Date: 2007-06-27
Since its original appearance in 1977, Advanced Organic Chemistry has maintained its place as the premier textbook in the field, offering broad coverage of the structure, reactivity and synthesis of organic compounds. As in the earlier editions, the text contains extensive references to both the primary and review literature and provides examples of data and reactions that illustrate and document the generalizations. While the text assumes completion of an introductory course in organic chemistry, it reviews the fundamental concepts for each topic that is discussed. The two-part fifth edition has been substantially revised and reorganized for greater clarity. Among the changes: Updated material reflecting advances in the field since 2001’s Fourth Edition, especially in computational chemistry; A companion Web site provides digital models for study of structure, reaction and selectivity; Solutions to the exercises provided to instructors online. The material in Part Ais organized on the basis of fundamental structural topics such as structure, stereochemistry, conformation and aromaticity and basic mechanistic types, including nucleophilic substitution, addition reactions, carbonyl chemistry, aromatic substitution and free radical reactions. Together with Part B: Reaction and Synthesis, the two volumes are intended to provide the advanced undergraduate or beginning graduate student in chemistry with a sufficient foundation to comprehend and use the research literature in organic chemistry.