Fractal Analysis And Synergetics Of Catalysis In Nanosystems
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Fractal Analysis and Synergetics of Catalysis in Nanosystems
Nanochemistry is a science connected with obtaining and studying of physical-chemical properties of particles having sizes on the nanometer scale. This book addresses polymer synthesis which, according to Melikhov's classification, is automatically part of nanochemistry. This is determined as far as polymeric macromolecules (more precisely macromolecular coils) belong to nanoparticles and polymeric sols and gels - to nanosystems. Catalysis on nanoparticles is one of the most important sections of nanochemistry. The majority of catalytic systems are nanosystems. At heterogeneous catalysis the active substance is tried to deposit on carrier in nanoparticles form in order to increase their specific surface. At homogeneous catalysis active substance molecules have often in themselves nanometer sizes. The most favorable conditions for homogeneous catalysis are created when reagent molecules are adsorbed rapidly by nanoparticles and are desorbed slowly but have high surface mobility and, consequently, high reaction rate on the surface and at the reaction molecules of such structure are formed at which desorption rate is increased sharply. If these conditions are realised in nanosystem with larger probability than in macrosystem, then nanocatalyst has the raising activity that was observed for many systems.
The Fractal Physics of Polymer Synthesis
Using fractal analysis, irreversible aggregation models, synergetics, and percolation theory, this book describes the main reactions of high-molecular substances. It is the first to give the structural and physical grounds of polymers synthesis and curing based on fractal analysis. It provides a single equation for describing the relationship betwe
Structure and Properties of Crosslinked Polymers
This book gives a fresh point of view on the curing processes, structure and properties of crosslinked polymers. The general view is that the structure and properties of crosslinked polymers are defined by their density, this book demonstrates that the parameters are defined by the supermolecular (a more precisely, supersegmental structure) of the crosslinked polymers.The quantitative relationships of the structures/properties are obtained for these polymers. Using an epoxy polymer as a nanofiller for a nanocomposite is discussed and a new class of polymer is proposed. The introduction of the nanofiller gives variation in the mechanical properties, degree of crystallinity, gas permeability and so on. The use of these crosslinked polymers as natural nanocomposites is proposed. Practical methods of crosslinked polymer's supersegmental structure regulation are considered, and all the changes that this gives their properties are detailed.This book will be of significance to all material scientists and students of material science.