Consequences Of Hydroxyl Generation By The Silica Water Reaction Part I Diffusion And Swelling

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Consequences of hydroxyl generation by the silica/water reaction - Part II: Global and local Swelling - Part III: Damage and Young's Modulus

Author: Fett, Theo
language: en
Publisher: KIT Scientific Publishing
Release Date: 2022-07-11
Water diffusing into silica surfaces gives rise for several effects on diffusion behaviour and mechanical properties. In a preceding booklet, we focused on diffusion and fiber strengths and deformations which were obtained by water soaking under external loading. In the present booklet we deal with results and interpretations of strength increase in the absence of applied stresses.
Consequences of hydroxyl generation by the silica/water reaction - Part I: Diffusion and Swelling

Author: Fett, Theo
language: en
Publisher: KIT Scientific Publishing
Release Date: 2022-07-11
Water diffusing into silica surfaces gives rise for several effectson diffusion behaviour and mechanical properties. Water added to silica glass increases its specific volume so that the silica expands near the surface. Mechanical boundary conditions give rise for compressive “swelling stresses”. This fact provides a tool for the interpretation of many experimental observations from literature.
Dynamic Model-based Analysis of Oxygen Reduction Reaction in Gas Diffusion Electrodes

Author: Röhe, Maximilian
language: en
Publisher: KIT Scientific Publishing
Release Date: 2024-01-09
In this work, the first simulation model of oxygen depolarized cathodes (ODC), which are silver catalyst-based gas diffusion electrodes, is presented that considers the phase equilibrium of the gas-liquid interface and structure-related inhomogeneities in electrolyte distribution. By means of the model it has been identified that mass transport of water and ions in the liquid phase is a crucial factor for electrode performance and how it is influenced by the electrode structure.