Compounds With Bonds Between Tin And Transition Metals Of Groups Viii I And Ii
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Compounds with Bonds between Tin and Transition Metals of Groups VIII, I, and II
Part 22 concludes the description of mononuclear organotin compounds containing bonds between tin and a transition metal. The Group-VIII compounds occupy the largest portion of this volume and are subdivided into the subgroups of iron, cobalt, and nickel. The molecular structure of many of these compounds has been elucidated in addition to the standard spectroscopic methods. Compounds of copper, silver, and gold, although virtually unknown, are included in the present volume, since several organotin cuprates have been prepared intermediately and used in situ as regio- and stereoselective reagents in organic chemistry.
Compounds of the Transition Elements Involving Metal-Metal Bonds
Compounds of the Transition Elements Involving Metal-Metal Bonds focuses on compounds of the transition elements involving metal-metal bonds. Emphasis is on metal-metal bonds in coordination compounds and organometallic complexes, halides, and oxides. Factors that influence the formation, stability, and properties of such compounds, as well as their application in various fields of chemistry and physics, are discussed. This book is divided into four sections and begins with a classification of metal-metal bonds and some of the physical and chemical methods used to study them, including X-ray crystallography, magnetic susceptibility and electron spin resonance, nuclear spin resonance, Mössbauer measurements, infrared and Raman spectroscopy, visible and ultraviolet spectroscopy, mass spectrometry, electrical conductivity, electrochemistry, and chemical reactivity. Factors influencing the strength of metal-metal bonds in metals and compounds are also examined. The remaining sections deal with metal-metal bonds in coordination compounds and organometallic complexes, halides, and oxides. This monograph will be a useful resource for inorganic chemists.
Compounds with Bonds between Tin and Transition Metals of Groups III to VII
Volume 21 describes mononuclear organotin compounds containing bonds between tin and transition metals of Groups III to VII; it includes a few compounds with tin-lanthanide and tin-actinide bonds. Compounds with Sn-Cr, Sn-Mo, Sn-W, and Sn-Mn bonds are most numerous and occupy a large portion of the volume. Many molecular structures are displayed to illustrate the geometry of -bonded organotin units and in several cases also the more complex bonding between the tin and transition metal moieties. All compounds ever reported are included in the present volume. If a compound was earlier described within the Gmelin series on organometallic compounds of the transition metals, reference to the respective location is made and new information is added when available in the literature.